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    Faraday's law of electrolysis predicts the mass of material that will be deposited at an electrode during electrolysis. It was originally stated as two separate laws by Michael Faraday in 1834.

        Faraday's law of electrolysis
            Original form
            Modern form
            See also

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    Original form
    Faraday's 1st Law of Electrolysis:

    The mass of a substance produced at an electrode during electrolysis is proportional to the number of moles of electrons (the quantity of electricity) transferred at that electrode.


    Faraday's 2nd Law of Electrolysis:

    The number of Faradays of electric charge required to discharge one mole of substance at an electrode is equal to the number of "excess" elementary charges on that ion.


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    Modern form
    In modern form, Faraday's law states:

    m = cdot = cdot = cdot

    = cdot

    where

    m is the mass of the substance produced at the electrode (in grams),

    Q is the total electric charge that passed through the solution (in coulombs),

    q is the electron charge = 1.602 x 10-19 coulombs per electron,

    n is the valence number of the substance as an ion in solution (electrons per ion),

    F = qN_A = 96,485 mathrm cdot mathrm is Faraday's constant,

    M is the molar mass of the substance (in grams per mole), and

    NA is Avogadro's number = 6.022 x 1023 ions per mole.


    In practice, the total charge Q is calculated by integrating the electric current I(t) over time t:
    Q = int_0^T I(t) cdot dt


    where T is the total amount of time of the electrolysis.

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    See also






     
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    Scientus.org Dictionary (Yet Another Wiki) RC : 1.39
    This article is licensed under the GNU Free Documentation License [copyleft]. It uses material from the Wikipedia article "Faraday's law of electrolysis". link